Kendriya Vidyalaya Question Papers Class 11 Chemistry

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Kendriya Vidyalaya Question Papers Class 11 Chemistry Objective for Students

Hoffmann’s rearrangement during the conversion of an amide to amine is

(A) Intramolecular

(B) Intermolecular

(C) Both

(D) None

Option a – Intramolecular

The number of p bonds present in CN-CH=CH-CN is ( Kendriya Vidyalaya Question Papers MCQ )

(A) 5

(B) 4

(C) 3

(D) 2

Option a – 5

Gabriel phthalimide reaction is used in the synthesis of

(A) Primary aromatic amines

(B) Secondary amines

(C) Primary aliphatic amines

(D) Tertiary amines

Option d – Tertiary amines

t-butyl isocyanide on reduction gives ( Kendriya Vidyalaya Question Papers MCQ )

(A) t-butylamine

(B) t-butyl methylamine

(C) t-butylethylamine

(D) None

Option b – t-butyl methylamine

Hydrolysis of alkyl isocyanide yields

(A) Primary amine

(B) Tertiary amine

(C) Alcohol

(D) Aldehyde

Option a – Primary amine

In disaccharides, the anomeric carbon of one monosaccharide is bonded to the carbon of another monosaccharide through ( Kendriya Vidyalaya Question Papers MCQ )

(A) Carbon

(B) Nitrogen

(C) Sulphur

(D) Oxygen

Option d – Oxygen

Glucose reacts with alcohol in the presence of dry HCl to give a cyclic hemiacetal. It shows that

(A) Formyl group and hydroxyl group are absent.

(B) Hydroxyl group is present.

(C) Formyl group is present.

(D) Hydroxyl group and formyl group are part of the same molecule.

Option d – Hydroxyl group and formyl group are part of the same molecule

The glycosidic linkage in carbohydrates is ( Kendriya Vidyalaya Question Papers MCQ )

(A) A link between C atoms in a carbohydrate through an oxygen atom formed by the elimination of water.

(B) A link between two carbon atoms in a carbohydrate by a covalent bond.

(C) A link between a carbon atom and an oxygen atom.

(D) A link between a carbon atom and a nitrogen atom.

Option a – A link between C atoms in a carbohydrate through an oxygen atom formed by the elimination of water

Sucrose molecule contains

(A) A glucofuranose and a fructofuranose units.

(B) A glucopyranose and a fructopyranose units.

(C) A glucopyranose and a fructofuranose units.

(D) A glucofuranose and a fructopyranose units.

Option c – A glucopyranose and a fructofuranose units

Benzyl amine is more …….. basic than aniline while ethyl amine is …… basic than diethyl amine ( Kendriya Vidyalaya Question Papers MCQ )

(A) More, less

(B) Less, more

(C) Both

(D) None

Option a – More, less

All classes of amines react with

(A) Water

(B) Acids

(C) Alkyl halides

(D) All the above

Option d – All the above

On reduction of Schiff’s base, we get ( Kendriya Vidyalaya Question Papers MCQ )

(A) Primary amine

(B) Secondary amine

(C) Anils

(D) Anilide

Option b – Secondary amine

This compound does not respond to the carbylamine reaction

(A) Isopropylamine

(B) Diethylamine

(C) t-Butylamine

(D) Sec-Butylamine

Option b – Diethylamine

Which reaction sequence would be best to prepare 3-chloroaniline from benzene? ( Kendriya Vidyalaya Question Papers MCQ )

(A) Chlorination, nitration, reduction

(B) Nitration, chlorination, reduction

(C) Nitration, reduction, chlorination

(D) Nitration, reduction, acetylation, chlorination, hydrolysis

Option b – Nitration, chlorination, reduction

Aniline is identified by

(A) Kolbe’s reaction

(B) Riemer-Tiemann reaction

(C) Carbylamine reaction

(D) Haloform reaction

Option c – Carbylamine reaction

Nitrobenzene on further excessive nitration gives ( Kendriya Vidyalaya Question Papers MCQ )

(A) sym-trinitrobenzene

(B) m-dinitrobenzene

(C) p-dinitrobenzene

(D) all of these

Option b – m-dinitrobenzene

Primary nitro compounds react with nitrous acid to form nitrolic acids which dissolve in NaOH giving

(A) yellow solution

(B) blue solution

(C) colorless solution

(D) red solution

Option d – red solution

Hinsberg’s reagent is ( Kendriya Vidyalaya Question Papers MCQ )

(A) Diethyl oxalate

(B) Benzyl chloride

(C) Benzene sulphonyl chloride

(D) None of these

Option c – Benzene sulphonyl chloride

Aqueous Bromination of aniline gives:

(A) 2-Bromoaniline

(B) 4-Bromoaniline

(C) 2,4,6-Tribromoaniline

(D) 2,6-Dibromoaniline

Option c – 2,4,6-Tribromoaniline

Ethylamine reacts with carbon disulphide in the presence of mercuric chloride and gives the main product ( Kendriya Vidyalaya Question Papers MCQ )

(A) Ethyl carbylamine

(B) Ethyl isonitrile

(C) Ethyl isothiocyanate

(D) Ethyl thiocyanide

Option c – Ethyl isothiocyanate

Aqueous solution of methylamine will be

(A) Acidic

(B) Basic

(C) Neutral

(D) Amphoteric

Option b – Basic

Which one of the following tests can be used to identify the primary amino group in a given organic compound ( Kendriya Vidyalaya Question Papers MCQ )

(A) Iodoform test

(B) Victor Meyer’s test

(C) Carbylamine reaction

(D) Liebermann’s reaction

Option a – Iodoform test

Weakest amine is

(A) Aniline

(B) Methylamine

(C) Dimethyl amine

(D) Ethylamine

Option a – Aniline

If primary amines are treated with ketones, the product is ( Kendriya Vidyalaya Question Papers MCQ )

(A) Urea

(B) Guanidine

(C) Amide

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(D) Schiff’s base

Option a – Urea

N, N-dimethyl acetamide is obtained in the reaction

(A) Acetyl chloride and methanamine

(B) Acetyl chloride and ethanamine

(C) Acetyl chloride and dimethylamine

(D) Acetyl chloride and diethylamine

Option c – Acetyl chloride and dimethylamine

A compound of molecular weight 180 g/mol is acetylated to give a compound of molecular weight 390 g/mol. The number of amino groups in the compound are ( Kendriya Vidyalaya Question Papers MCQ )

(A) 2

(B) 4

(C) 5

(D) 6

Option c – 5

Propylamine reacts with nitrous acid to form a relatively stable cation viz.

(A) Propyl diazonium ion

(B) Isopropyl carbocation

(C) Isopropyl diazonium ion

(D) Propyl carbonium ion

Option b – Isopropyl carbocation

Which of the following does not form a sulfur compound with a primary amine ( Kendriya Vidyalaya Question Papers MCQ )

(A) Hinsberg’s reagent

(B) Sulfuric acid

(C) Schotten-Boumann reaction

(D) Mustard oil reaction

Option c – Schotten-Boumann reaction

False statement regarding amines is:

(A) They give mustard oil reaction

(B) They give carbylamine reaction

(C) They form salt with acids

(D) They give alcohol on hydrolysis

Option d – They give alcohol on hydrolysis

Which of the following compounds gives an explosive on decarboxylation ( Kendriya Vidyalaya Question Papers MCQ )

(A) 2,4, 6-Trinitrobenzoic acid

(B) 2, 4-Dinitrobenzoic acid

(C) o-Aminobenzoic acid

(D) o-Hydroxy benzoic acid

Option a – 2,4, 6-Trinitrobenzoic acid

Aniline is purified by:

(A) Azeotropic distillation

(B) Steam distillation

(C) Distillation in the presence of magnesium

(D) Fractional distillation

Option b – Steam distillation

Aniline on treatment with bromine water yields a white precipitate of ( Kendriya Vidyalaya Question Papers MCQ )

(A) o-Bromoaniline

(B) p-Bromonailine

(C) 2, 4, 6-Tribromoaniline

(D) m-Bromoaniline

Option c – 2, 4, 6-Tribromoaniline

Which of the following is the most basic:

(A) Aniline

(B) o-Nitroaniline

(C) m-Nitroaniline

(D) p-Nitroaniline

Option a – Aniline

The lowest boiling point will be of the compound ( Kendriya Vidyalaya Question Papers MCQ )

(A) Ethylamine

(B) Ethylmethylamine

(C) 1-propanamine

(D) N, N-dimethylmethanamine

Option d – N, N-dimethylmethanamine

The solubility of ethylamine in water is due to:

(A) Low molecular weight

(B) Ethyl group is present in ethyl alcohol

(C) Formation of H-bonding with water

(D) Being a derivative of ammonia

Option c – Formation of H-bonding with water

The lowest boiling point will be of the compound ( Kendriya Vidyalaya Question Papers MCQ )

(A) Ethylamine

(B) Ethylmethylamine

(C) 1-Propaneamine

(D) N,N-Dimethylmethanamine

Option a – Ethylamine

The odor of alkyl cyanides is similar to –

(A) Bitter almonds

(B) Acid

(C) Fruity smell

(D) None

Option a – Bitter almonds

Which of the following compounds gives the smell of mustard oil ( Kendriya Vidyalaya Question Papers MCQ )

(A) Alkyl isocyanate

(B) Alkyl isothiocyanate

(C) Alkyl isocyanide

(D) Alkyl isonitrile

Option b – Alkyl isothiocyanate

The basic character of amines can be explained

(A) In terms of Lewis and Arrhenius concept

(B) In terms of Lowry and Bronsted concept

(C) In terms of Lewis and Lowry Bronsted concept

(D) Only by Lewis concept

Option c – In terms of Lewis and Lowry Bronsted concept

The number of resonating structures of anilinium ion is ( Kendriya Vidyalaya Question Papers MCQ )

(A) 2

(B) 3

(C) 4

(D) 5

Option a – 2

Hydrolysis of benzonitrile gives

(A) benzylamine

(B) aniline

(C) benzoic acid

(D) benzene

Option c – benzoic acid

Butane nitrile may be prepared by heating ( Kendriya Vidyalaya Question Papers MCQ )

(A) propyl alcohol with KCN

(B) butyl alcohol with KCN

(C) butyl chloride with KCN

(D) propyl chloride with KCN

Option d – propyl chloride with KCN

Gabriel phthalimide reaction is used for the preparation of

(A) primary aromatic amines

(B) secondary amines

(C) primary aliphatic amines

(D) tertiary amines

Option c – primary aliphatic amines

Which of the following is not an explosive? ( Kendriya Vidyalaya Question Papers MCQ )

(A) Nitroglycerine

(B) o-Aminotoluene

(C) Dynamite

(D) Trinitrotoluene

Option b – o-Aminotoluene

Reduction of acetaldoxime gives:

(A) Ethylamine

(B) Acetaldehyde

(C) Dimethylamine

(D) Methylcarbamide

Option a – Ethylamine

Mendius reaction involves the reduction of ( Kendriya Vidyalaya Question Papers MCQ )

(A) Cyanoalkanes

(B) Alkyl isocyanides

(C) Oximes

(D) Nitroalkanes

Option a – Cyanoalkanes

Gabriel’s reaction to the synthesis of amines involves the use of:

(A) 1° amide

(B) 2° amide

(C) Cyclic imide

(D) Aliphatic amide

Option c – Cyclic imide

Ethylamine can be prepared by all except ( Kendriya Vidyalaya Question Papers MCQ )

(A) Curtius reaction

(B) Hofmann reaction

(C) Mendius reaction

(D) Reduction of formaldoxime

Option d – Reduction of formaldoxime

Which of the following methods is generally not employed for the separation of primary, secondary, and tertiary amines?

(A) Fractional distillation

(B) Hinsberg’s method

(C) Hofmann’s method

(D) Filtration

Option d – Filtration

The chain isomer of butanal is

(A) 2-methyl propan-1-ol

(B) 2-methyl propan-1-al

(C) 2-methyl butan-1-ol

(D) 2-methyl butanal

Option b – 2-methyl propan-1-al

Propionaldehyde and acetone are

(A) Chain isomers

(B) Position isomers

(C) Functional isomers

(D) Tautomers

Option c – Functional isomers

The tautomer of acetaldehyde is

(A) Crotyl alcohol

(B) Allyl alcohol

(C) Benzyl alcohol

(D) Vinyl alcohol

Option d – Vinyl alcohol

Select the correct IUPAC name for salicylic acid

(A) 2-methyl benzoic acid

(B) 2-hydroxy benzoic acid

(C) 2-hydroxy butanedioic acid

(D) Hexanedioic acid

Option b – 2-hydroxy benzoic acid

From Goat, the substance obtained is

(A) Caproic acid

(B) Carbolic acid

(C) Valeric acid

(D) Butyric acid

Option a – Caproic acid

Aliphatic tricarboxylic acid is

(A) Citric acid

(B) Phthalic acid

(C) Tartaric acid

(D) Oxalic acid

Option a – Citric acid

Pentan-2-one and 3-methyl butan-2-one are

(A) Functional isomers

(B) Optical isomers

(C) Chain isomers

(D) Metamers

Option c – Chain isomers

The enolic form of acetone contains

(A) 9 sigma bonds, 2 pi bonds, and 1 lone pair

(B) 10 sigma bonds, 1 pi bond, and 1 lone pair

(C) 8 sigma bonds, 2 pi bonds, and 2 lone pairs

(D) 9 sigma bonds, 1 pi bond, and 2 lone pairs.

Option d – 9 sigma bonds, 1 pi bond, and 2 lone pairs

A functional isomer of ethanoic acid is

(A) Methyl methanoate

(B) Methyl ethanoate

(C) Ethyl formate

(D) Ethyl acetate

Option a – Methyl methanoate

Methyl ethanoate and ethyl methanoate are

(A) Metamers

(B) Tautomers

(C) Functional isomers

(D) Chain isomers

Option a – Metamers

3-Hydroxypropanal functional isomer is

(A) Propionic acid

(B) 1-Hydroxy propan-2-one

(C) 3-Hydroxy propionate

(D) Ethyl methyl ketone

Option b – 1-Hydroxy propan-2-one

Select the correct IUPAC name of n-butyrophenone

(A) 1-phenyl butan-1-one

(B) Phenyl-n-propyl ketone

(C) Cinnamaldehyde

(D) Vanillin

Option a – 1-phenyl butan-1-one

m-toluic acid and p-toluic acid are

(A) Chain isomers

(B) Functional isomers

(C) Tautomers

(D) Position isomers

Option d – Position isomers

Diethyl ketone and methyl n-propyl ketone are

(A) Chain isomers.

(B) Optical isomers

(C) Metamers

(D) Tautomers

Option c – Metamers

The oxidation product of pentan-2-ol is

(A) Valeraldehyde

(B) Diethyl ketone

(C) Methyl n-propyl ketone

(D) Pentan-3-one

Option c – Methyl n-propyl ketone

Alkanal is obtained by ozonolysis of

(A) Alkene

(B) Alkane

(C) Aldehyde

(D) Ether

Option a – Alkene

Propanone is obtained by the decomposition of ozonide of

(A) Isobutylene

(B) 2-Methyl but-2-ene

(C) 3,4-Dimethyl hex-3-ene

(D) 2,3-Dimethyl but-2-ene

Option d – 2,3-Dimethyl but-2-ene

Ethanal is prepared by ozonolysis of

(A) But-1-ene

(B) But-2-ene

(C) 2-Methyl prop-1-ene

(D) Ethene

Option c – 2-Methyl prop-1-ene

Alkyne produce alkanal on hydration is

(A) Acetylene

(B) Propyne

(C) Dimethyl acetylene

(D) Ethyl acetylene

Option a – Acetylene

Propanone is the hydration product of

(A) Ethene

(B) Propene

(C) Propyne

(D) But-2-yne

Option c – Propyne

Dimethyl acetylene on hydration produces

(A) Butyraldehyde

(B) Ethyl methyl ketone

(C) Sec. butyl alcohol

(D) 2-Methyl propanal

Option b – Ethyl methyl ketone

The stable hydrolysis product of isopropylidene hydrogen sulfate is

(A) Propan-1-ol

(B) Propyne

(C) Propan-1-al

(D) Propan-2-one

Option d – Propan-2-one

Dehydrogenation product of sec. butyl alcohol is

(A) Valeraldehyde

(B) Butyric acid

(C) Butanone

(D) But-2-ene

Option c – Butanone

Which of the following compound reacts with phenyl magnesium bromide and formed product on acid hydrolysis gives

(A) Benzonitrile

(B) Pent-3-en nitrile

(C) 2-Phenyl ethane nitrile

(D) 3-Phenyl propane

Option a – Benzonitrile

Chromium complex, prepared from methyl benzene and chromyl chloride on hydrolysis gives

(A) Methyl phenyl ketone

(B) Benzoic acid

(C) Benzaldehyde

(D) Salicylic acid

Option c – Benzaldehyde

Preparation of benzaldehyde from toluene using chromyl chloride is …… reaction.

(A) Esterification

(B) Reduction

(C) Hydrolysis

(D) Oxidation

Option d – Oxidation

A mixture of carbon monoxide and hydrochloric acid when passed through solution of benzene in ether containing An.aluminium trichloride gives

(A) Carbolic acid

(B) Benzene carboxylic acid

(C) Bromobenzene

(D) Benzene carbaldehyde

Option d – Benzene carbaldehyde

Alkyl cyanides treated with alkyl magnesium halide gives addition complex which on hydrolysis

(A) Alcohols

(B) Aldehydes

(C) Ketones

(D) Esters

Option c – Ketones

Ethanal is not prepared from

(A) Formonitrile + G.R.

(B) Ethylidene dichloride by hydrolysis

(C) Acetonitrile by Stephen’s reaction

(D) Ethen-1-nitrile

Option a – Formonitrile + G.R

Ethyl benzoate on alkaline hydrolysis gives:

(A) Alkali benzoate and ethyl alcohol

(B) Carbolic acid and ethanoic acid

(C) Benzoic acid and alkali ethoxide

(D) Benzoic acid and ethyl alcohol

Option a – Alkali benzoate and ethyl alcohol

Alkane nitriles prepared from isopropyl bromide and potassium cyanide on acid hydrolysis give:

(A) n-Propionic acid

(B) n-Butyric acid

(C) Isopropionic acid

(D) Isobutyric acid

Option d – Isobutyric acid

Benzoic acid is the acid hydrolysis product of:

(A) Benzoyl chloride

(B) Benzonitrile

(C) Benzamide

(D) All of the above

Option d – All of the above

Benzoyl chloride on treating with water produces:

(A) Phenyl methanol

(B) Benzene

(C) Benzoic acid

(D) Benzene carbaldehyde

Option c – Benzoic acid

Benzal chloride prepared from toluene and chlorine in the presence of UV light on hydrolysis gives:

(A) Benzophenone

(B) Benzyl alcohol

(C) Benzaldehyde

(D) Acetophenone

Option c – Benzaldehyde

Acetophenone is prepared by reacting ethanoyl chloride and:

(A) Methane

(B) Propane

(C) Butane

(D) Benzene

Option d – Benzene

Benzophenone is prepared by Friedel-Craft reaction from:

(A) Methyl phenyl ketone and benzene

(B) Ethanoyl chloride and benzene

(C) Benzoyl chloride and benzene

(D) Bromobenzene and benzene

Option c – Benzoyl chloride and benzene

Formylation of benzene or toluene by CO + HCl is:

(A) Rosenmund’s reaction

(B) Stephen’s reaction

(C) Gattermann-Koch synthesis

(D) Wurtz reaction

Option c – Gattermann-Koch synthesis

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