Haloalkanes and Haloarenes JEE Mains Questions

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Haloalkanes and Haloarenes JEE Mains Objective Questions for Students

Isopropyl iodide on boiling with aq.KOH produces

(A) n-propyl carbinol

(B) Ethyl methyl carbinol

(C) Dimethyl carbinol

(D) Diethyl carbinol

Option c – Dimethyl carbinol

Ethyl isocyanide is obtained by boiling with ethyl iodide and

(A) Alcoholic silver cyanide

(B) Alcoholic potassium cyanide

(C) Alcoholic silver salt of the acid

(D) Alcoholic sodium cyanide

Option a – Alcoholic silver cyanide

Ethyl bromide on heating with alcoholic silver nitrite gives

(A) CH3-CH2-COOAg

(B) CH3-CH2-NO2

(C) CH3-CH2-O-N=O

(D) CH3-CH2-NH2

Option b – CH3-CH2-NO2

Chloroethane on heating with sodium tertiary butoxide form

(A) 2-ethoxy-2-methyl propane

(B) 2-ethoxy-2-methyl butane

(C) 1-ethoxy-1,1-dimethyl propane

(D) 2-methoxy-2-methylpropane

Option a – 2-ethoxy-2-methyl propane

Chloroform derivatives of methane are

(A) Westron

(B) Freon

(C) Resins

(D) Dichloro diphenyl trichloroethane

Option b – Freon

1°, 2°, 3°, and quaternary ammonium salt can be prepared from haloalkanes by

(A) Mayers process

(B) Hoffmann’s ammonolysis

(C) Groove’s ammonolysis

(D) Newmann’s reaction

Option b – Hoffmann’s ammonolysis

In Grignard’s reagent, the R-group is present in the form of

(A) Free radical

(B) Carbocation

(C) Carbanion

(D) Any of the above

Option c – Carbanion

Exposure to which of the compound can cause liver cancer?

(A) Dichlorodifluoromethane

(B) Chloromethane

(C) Trichloromethane

(D) Carbon tetrachloride

Option d – Carbon tetrachloride

Williamson’s synthesis is the preparation of …… from haloalkanes.

(A) Ketones

(B) Alcohols

(C) Ethers

(D) Esters

Option c – Ethers

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