MCQ Questions for Class 11 Chemistry Chapter 1

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MCQ Questions for Class 11 Chemistry Chapter 1. We covered all the MCQ Questions for Class 11 Chemistry Chapter 1 in this post for free so that you can practice well for the exam.

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MCQ Questions for Class 11 Chemistry Chapter 1 Objective

One of the products formed due to the re-action between KMnO4 and HCI is

(A) red liquid

(B) MnO2

(C) greenish yellow gas

(D) HCIO4

Option c – greenish yellow gas

Which of the following is not an element?

(A) Graphite

(B) Diamond

(C) 22-Carat gold

(D) Rhombic sulphur

Option c – 22-Carat gold

Green vitriol is

(A) FeSO4.7H₂O

(B) ZnSO4.7H₂O

(C) CaSO4 2H₂O

(D) CuSO4.5H₂O

Option a – FeSO4.7H₂O

Wrought iron, pig iron and steel differ in properties due to

(A) carbon content

(B) malleability

(C) conductivity

(D) softness

Option a – carbon content

The oxidation state of chromium in the final product formed by the reaction between KI and acidified potassium dichromate solution is.

(A) +4

(B) +6

(C) +2

(D) +3

Option d – +3

How many electrons are involved in the oxidation by KMnO4 in basic medium?

(A) 1

(B) 2

(C) 5

(D) 3

Option a – 1

The number of unpaired electrons in a nickel atom (ground state) are (At. No. of Ni = 28)

(A) 2

(B) 5

(C) 3

(D) 7

Option a – 2

Which one of the following compounds does not decolourise an acidified aqueous solution of KMnO4?

(A) Sulphur dioxide

(B) Ferric chloride

(C) Hydrogen peroxide

(D) Ferrous sulphate

Option b – Ferric chloride

Which of the following contains the maximum number of unpaired electrons

(A) TiCl3

(B) MnCl2

(C) FeSO4

(D) CuSO4

Option b – MnCl2

In Cu (Z = 29)

(A) 13 electrons have spin in one direction and 16 electrons in other direction

(B) 14 electrons have spin in one direction and 15 electrons in other direction

(C) all the electrons have spin in one direction

(D) none of these

Option b – 14 electrons have spin in one direction and 15 electrons in other direction

(NH4)2SO4. FeSO4.6H2O is

(A) Mohr’s salt

(B) Alum

(C) Blue vitriol

(D) Simple salt

Option a – Mohr’s salt

In the chemical reaction Ag2O + H₂O + 2e-2Ag + 2OH

(A) water is oxidised

(B) electrons are reduced

(C) silver is oxidised

(D) silver is reduced

Option d – silver is reduced

Which of the following compounds is expected to be coloured?

(A) Ag2SO4

(B) CuF2

(C) MgF2

(D) CuCl

Option b – CuF2

In the preparation of KMnO4, pyrolusite (MnO2) is first converted to potassium manganate (K2MnO4). In this conversion, the oxidation state of manganese changes from

(A) + 1 to +3

(B) +2 to +4

(C) +3 to +5

(D) +4 to +6

Option d – +4 to +6

Ionic character of halides of metals (3d-transition series) decreases in the order

(A) M-I > M-Br > M-CI > M-F

(B) M-CI > M-Br > M-1 > M-F

(C) M-Br > M-CI > M-F> M-I

(D) M-F> M-CI > M-Br > M-I

Option d – M-F> M-CI > M-Br > M-I

Which of the following group of transition metals is called coinage metals

(A) Cu, Ag, Au

(B) Ru, Rh, Pd

(C) Fe, Co, Ni

(D) Os, Ir, Pt

Option a – Cu, Ag, Au

At 20°C, the vapour pressure of diethyl ether is 442 mm. When 6.4 g of a non-volatile solute is dissolved in 50 g of solvent, the vapour pressure of the solution becomes 410 mm. The molecular mass of the solute is

(A) 150

(B) 130.9

(C) 160

(D) 180

Option b – 130.9

One molar glucose solution boils at 100.54°C. The relative decrease in vapour pressure of aq. urea solutions are 0.018. The elevation in the boiling point of the urea solution is

(A) 0.18°C

(B) 0.36°C

(C) 0.72°C

(D) 0.54°C

Option d – 0.54°C

A solution containing 0.1 g of non-volatile solute P (molar mass 100 g) in 100 g of benzene gives rise in boiling point by 0.2 K. Another solution containing 0.1 g of ‘Q’ non-volatile solute in the same amount of the same solvent gives elevation in B.P. by 0.4 K. The ratio of the molar mass of P and Q is

(A) 1 : 2

(B) 2 : 1

(C) 1 : 4

(D) 4 : 1

Option b – 2 : 1

An aq. solution of sucrose-containing 34.2 g has an osmotic pressure of 2.38 atm at 17°C for an aq. solution of glucose to be isotonic with this solution would have mass

(A) 34.2 g

(B) 17.1 g

(C) 18.0 g

(D) 36.0 g

Option c – 18.0 g

The osmotic pressure of 5% (M/V) solution of sugar at 150°C is

(A) 4 atm

(B) 5.07 atm

(C) 3.55 atm

(D) 2.45 atm

Option b – 5.07 atm

30 g of a solute is added to 90 g of water, and the V.P. of the solution is 21.85 mm at 25°C. If 18 g of water is added to the same solution. V.P. of the solution becomes 22.15 mm. The vapour pressure of the solvent is

(A) 21.35 mm

(B) 75.6

(C) 12:35 mm

(D) 35.21 mm

Option a – 21.35 mm

The isotonic solution has equal

(A) Vapour pressure

(B) Osmotic pressure

(C) Solution pressure

(D) Freezing point

Option b – Osmotic pressure

The ratio of the value of any colligative property of KCl solution to that of sugar solution is

(A) 1

(B) 0.5

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(C) 2

(D) 4

Option c – 2

An aqueous solution containing 1 g urea boils at 100.25°C. The aq. solution containing 3 g of glucose in the same volume will boil at

(A) 100.75°C

(B) 100.50°C

(C) 100.25°C

(D) 100°C

Option c – 100.25°C

A compound that acts as a semipermeable membrane is

(A) Calcium sulphate

(B) Nickel phosphate

(C) Barium oxalate

(D) Copper ferrocyanide

Option d – Copper ferrocyanide

Ebullioscopy is concerned with

(A) Osmotic pressure of the solution

(B) Boiling point elevation

(C) Relative lowering in vapour pressure

(D) Freezing point depression

Option b – Boiling point elevation

The osmotic pressure of 0.2 M urea solution at 27°C is

(A) 4.92 atm

(B) 0.29 atm

(C) 9.24 atm

(D) 2.49 atm

Option a – 4.92 atm

The osmotic pressure of the solution increase if

(A) Temperature decreases

(B) the Concentration of solution decreases

(C) No. of solute molecules increases

(D) the Volume increases

Option c – No. of solute molecules increases

The solution having the highest boiling point is

(A) 0.05 M glucose

(B) 0.01 M KNO3

(C) 0.015 M urea

(D) 0.01 M Na₂SO4

Option d – 0.01 M Na₂SO4

Which one is known as oil of vitriol?

(A) H₂SO3

(B) H₂SO4

(C) H₂S₂O7

(D) H₂S₂O8

Option b – H₂SO4

In the preparation of sulphuric acid, V₂O5 is used in the reaction, which is

(A) S + O₂ → SO₂

(B) 2SO2 + O2 →2SO3

(C) SO2 + H₂O → H₂SO3

(D) N₂ + 3H₂ → 2NH3

Option b – 2SO2 + O2 →2SO3

The bond angle in H₂S is

(A) 109°28′

(B) 104°5′

(C) 120°

(D) 92.5°

Option d – 92.5°

The sulfur molecule S8 possesses

(A) a Cubical structure

(B) a Spherical structure

(C) a Tetrahedral structure

(D) a W-shaped ring structure

Option d – a W-shaped ring structure

The correct order of electron affinity of B, C, Ni, and O is

(A) O> C>N> B

(B) B>N> C>O

(C) O> C> B>N

(D) O> B> C> N

Option d – O> B> C> N

The hybridization of sulfur in SO₂ is

(A) sp

(B) sp³

(C) sp³

(D) dsp²

Option c – sp³

Which of the following compounds contains S=O as well as S = S bonds?

(A) Sulphuric acid

(B) Thiosulphuric acid

(C) Sulphurous acid

(D) Thiosulphurous acid

Option c – Sulphurous acid

The geometry of H₂S and its dipole moment is

(A) Angular and non-zero

(B) Angular and zero

(C) Linear and non-zero

(D) Linear and zero

Option a – Angular and non-zero

The correct order of O-O bond length (increasing) in O2, H₂O2, and O3 is

(A) H₂O2 < O3 < O₂

(B) O₂ < 03 <H₂O₂

(C) O₂ < 03 < H₂O₂

(D) O3 <H₂O2 < O₂

Option b – O₂

The bond angle is minimum for

(A) H₂O

(B) H₂S

(C) H₂Se

(D) H₂Te

Option d – H₂Te

Which of the following mixture is chromic acid?

(A) K₂Cr₂O7 and conc. H₂SO4

(B) K₂Cr₂O7 and HCI

(C) K₂SO4 and HCI

(D) H₂SO4 and HCI

Option a – K₂Cr₂O7 and conc. H₂SO4

Carbogen is

(A) Pure from carbon

(B) COCI2

(C) a mixture of CO and CO₂

(D) a Mixture of O2 and CO₂

Option d – a Mixture of O2 and CO₂

The bleaching action of SO₂ is due to

(A) Reduction

(B) Oxidation

(C) Hydrolysis

(D) Its acidic nature

Option a – Reduction

The trioxides which can exist as the monomeric molecule is

(A) SO3 in a gaseous state

(B) TeO3

(C) SO3 in a solid state

(D) SeO3

Option a – SO3 in a gaseous state

The standard heat of combustion of carbon, hydrogen, and CH4 are -349, -241.8, and -906.7 kJ respectively. The std. the heat of formation of CH4 is

(A) 174.1 kJ

(B) 274.1 kJ

(C) 374.1 kJ

(D) 74.1 kJ

Option d – 74.1 kJ

40-joule heat is supplied to the system and work done by a system is 8 joule. Increase in internal energy of the system

(A) 25 J

(B) 30 J

(C) 32 J

(D) 28 J

Option c – 32 J

In the isochoric process, the increase in internal energy is equal to

(A) Heat absorbed

(B) Heat evolved

(C) Work done

(D) Heat absorbed and work done

Option a – Heat absorbed

A system in which there is no exchange of matter, work, or energy from the surrounding is

(A) Closed

(B) Isolated

(C) Adiabatic

(D) Isothermal

Option b – Isolated

An adiabatic process occurs in

(A) Open system

(B) Closed system

(C) Isolated system

(D) In all system

Option c – Isolated system

In the isothermal expansion of a gas

(A) Internal energy increases

(B) Enthalpy decreases

(C) Enthalpy remains unaffected

(D) Enthalpy reduced to zero

Option c – Enthalpy remains unaffected

According to Hess’s law, the heat of reaction. depends upon

(A) the Initial state of reactants

(B) the Initial and final state of reactants

(C) the Intermediate path of the reaction

(D) the End point of conditions of the reactant

Option b – the Initial and final state of reactants

Intensive properties among the following are

(A) Specific heat, and temperature

(B) Entropy, density

(C) Enthalpy, mole fraction

(D) Heat, temperature

Option a – Specific heat, and temperature

Which of the following is not a state function? (i) q + W (ii) q (iii) W (iv) HTS

(A) (i), (ii), (iii)

(B) (ii) and (iii)

(C) (i), (iv)

(D) (ii), (iii), (iv)

Option b – (ii) and (iii)

Which one of the following statements regarding starch and cellulose is not correct?

(a) Both of them are of plant origin.

(b) Both of them are polymers.

(c) Both of them give color with iodine.

(d) Both of them are made up of glucose molecules.

Option c – Both of them give color with iodine

Among the following sweeteners, which one has the lowest sweetness value?

(a) Alitame

(b) Aspartame

(c) Saccharin

(d) Sucralose

Option b – Aspartame

Which one of the following artificial sweeteners is modified sugar?

(a) Aspartame

(b) Succharin

(c) Sucralose

(d) Alitame

Option c – Sucralose

Glucose is a source of energy, which one of the following types of molecule is glucose?

(a) Carbohydrate

(b) Protein

(c) Fat

(d) Nucleic acid

Option a – Carbohydrate

Lactose on hydrolysis gives

(a) glucose

(b) fructose

(c) fructose + glucose

(d) glucose + galactose

Option d – glucose + galactose

Which one of the following carbohydrates is used for the silvering of a mirror?

(a) Sucrose

(b) Maltose

(c) Glucose

(d) Fructose

Option c – Glucose

The reagent which may be used to distinguish between cane sugar and glucose solution is

(a) Molisch’s reagent

(b) Iodine solution

(c) Baeyer’s reagent

(d) Fehling’s solution

Option d – Fehling’s solution

In honey, which one among the following sugars predominates?

(a) Sucrose

(b) Fructose

(c) Galactose

(d) Maltose

Option b – Fructose

The chemical name of vitamin A is

(a) thiamine

(b) axerophthol (retinol)

(c) ascorbic acid

(d) nicothamide

Option a – axerophthol (retinol)

The metal present in Vitamin B₁₂ is

(a) Iron

(b) Manganese

(c) Cobalt

(d) Magnesium

Option c – Cobalt

Which one of the following vitamins is essential for the coagulation of blood?

(a) Vitamin-A

(b) Vitamin-B12

(c) Vitamin-K

(d) Vitamin-D

Option c – Vitamin-K

Which one of the following acids is also known as Vitamin-C?

(a) Methanoic acid

(b) Ascorbic acid

(c) Lactic acid

(d) Tartaric acid

Option b – Ascorbic acid

Which of the following has a coiled helical structure?

(a) Proteins

(b) Lipids

(c) Carbohydrates

(d) Vitamins

Option a – Proteins

Which one of the following polymers is made of proteins?

(a) Rubber

(b) Cotton

(c) Wool

(d) Jute

Option c – Wool

What is the bond between two amino acids in a protein called?

(a) Ester bond

(b) Glycosidic bond

(c) Peptide bond

(d) Phosphodiester bond

Option c – Peptide bond

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